Technological and economic analysis of electrokinetic remediation of contaminated soil: A global perspective and its application in Indian scenario.

Globally million hectares of land annually is getting contaminated by heavy metalloids like As, Cd, Cr, Hg, Pb, Co, Cu, Ni, Zn, and Se, with current concentrations in soil above geo-baseline or regulatory standards. The heavy metals are highly toxic, mobile, and persistent and hence require immediate and effective mitigation. There are many available remediation techniques like surface capping, encapsulation, landfilling, soil flushing, soil washing, electrokinetic extraction, stabilization, solidification, vitrification, phytoremediation, and bioremediation which have been evolved to clean up heavy metal-contaminated sites. Nevertheless, all of the technologies have some applicability and limitations making the soil remediation initiative unsustainable. Among the available technologies, electrokinetic remediation (EKR) has been comparatively recognized to mitigate contaminated sites via both in-situ and ex-situ approaches due to its efficiency, suitability for use in low permeability soil, and requirement of low potential gradient. The work critically analyzes the EKR concerning techno, economic, and sustainability aspect for evaluating its application on various substrates and environmental conditions. The current soil contamination status in India is presented and the application of EKR for the heavy metal remediation from soil has been evaluated. The present work summaries a comprehensive and exhaustive review on EKR technology proving its effectiveness for a country like India where the huge amount of waste generated could not be treated due to lack of infrastructure, technology, and economic constraints.

Removal of nutrients and other emerging inorganic contaminants from water and wastewater by electrocoagulation process.

The continual discharge of emerging inorganic pollutants into natural aquatic systems and their negative effects on the environment have motivated the researchers to explore and develop clean and efficient water treatment strategies. Electrocoagulation (EC) is a rapid and promising pollutant removal approach that does not require any chemical additives or complicated process management. Therefore, inorganic pollutant treatment via the EC process is considered one of the most feasible processes. The potential developments of EC process may make the process a wise choice for water treatment in the future. Thus, the present study mainly focuses on the use of EC technology to remove nutrients and other emerging inorganic pollutants from water medium. The operating factors that influence EC process efficiency are explained. The major advancement of the EC technique as well as field-implemented units are also discussed. Overall, this study mainly focuses on emerging issues, present advancements, and techno-economic considerations in EC process.

Treatment of dairy industry wastewater by combined aerated electrocoagulation and phytoremediation process.

As dairy industries has been emerged as one of the most rapidly developing industry in both small as well as large scale, the volume of effluent generated is also very high. In the present study, aerated electrocoagulation combined with phytoremediation treatment was conducted in dairy industry wastewater. Electrocoagulation was performed with aluminium and iron electrodes and effect of various operating parameters such as electrode combination, pH, and voltage were tested. Electrocoagulation was found effective at neutral pH and its efficiency increased with increase in applied voltage. The maximum COD removal efficiency of 86.4% was obtained in case of Al-Fe electrode combination with aeration at 120 min reaction time, initial pH 7, voltage 5 V. Significant growth of Canna indica was observed in electrocoagulation treated wastewater compared to raw dairy wastewater. COD removal of 97% was achieved when combined electrocoagulation and phytoremediation process was used. Thus, it proves to be a proficient method for the treatment of dairy industry wastewater. In addition to the above, bacterial toxicity tests were performed to investigate the toxic nature of wastewater and the results showed that both treated and untreated wastewater favoured bacterial growth.